Emergent organocopper complexes as robust catalysts for electrosynthesis. The capture and stabilisation of highly reactive chemical species is critical to making advances in the synthesis of novel mat

Description

Emergent organocopper complexes as robust catalysts for electrosynthesis. The capture and stabilisation of highly reactive chemical species is critical to making advances in the synthesis of novel materials, agrochemicals and pharmaceuticals. Metal-bound carbanions are essential components of carbon-carbon bond forming reactions. This project aims to develop an unprecedented family of copper catalysts and deliver an innovative and versatile chemical reactivity platform. Expected outcomes of this project include methods of tempering and unleashing the high reactivity of these species by controlling the oxidation state of the copper ion. Benefits of these outcomes include fundamental understanding of the reactivity of a new class of copper complex that has potential commercial applications in catalysis.. Scheme: Discovery Projects. Field: 3402 - Inorganic Chemistry. Lead: Prof Paul Bernhardt